Four Renegades of Battery Failure

Declining Capacity

Energy storage in a battery can conceptually be divided into three imaginary segments of the available energy,the empty zonethat can be refilled, and the unusable part(rock content). Figure 1 illustrates these three sections.

Aging battery

 

 

Figure 1: Aging battery

Batteries begin fading from the day they are manufactured.A new battery should deliver 100 percent capacity; most packs in use operate at less.

Courtesy of Cadex

Although the manufacturer specifies the runtime of portable equipment based on a battery performing at 100 percent, most packs in the field operate at less capacity. As time goes on, the performance declines further and the battery gets smaller in terms of holding capacity. A pack should be replaced when the capacity drops to 80 percent. This is only 20 percent down from 100 percent, and the end-of-life threshold may vary according to application and company policy.

Besides age-related losses, sulfation and grid corrosion are the main killers of lead acid batteries. Sulfation is a thin layer that forms on the negative cell plate if the battery is allowed to dwell in a low state-of-charge. If sulfation is caught in time, an equalizing charge can reverse the condition. Read more about Sulfation. With nickel-based batteries, the so-called rock content is often the result of crystalline formation, also known as “memory,” and a full discharge can sometimes restore the battery. The aging process of lithium-ion is cell oxidation, a process that occurs naturally as part of usage and aging and cannot be reversed.

Rising Internal Resistance

High capacity has limited use if the battery is unable to deliver the stored energy effectively. To bring the power out, the battery needs low internal resistance. Measured in milliohms (mΩ), resistance is the gatekeeper of the battery; the lower the value, the less restriction the pack encounters. This is especially important with heavy loads and high current pulses, as elevated resistance causes the voltage to collapse and trigger an earlyshutdown. The device turns off and valuable energy is left behind. Figure 2 illustrates batteries with low and high internal resistance as free-flowing and restricted taps.

Effects of internal battery resistance

Effects of internal battery resistance

 

Figure 2: Effects of internal battery resistance

A battery with low internal resistance delivers high current on demand. High resistance causes the battery voltage to collapse. The equipment cuts off, leaving energy behind.

Courtesy of Cadex

Lead acid has a very low internal resistance, and the battery responds well to high current bursts lasting for only a few seconds. Due to inherent sluggishness, however, lead acid does not perform well with a sustained discharge at high current and the battery needs rest to recover. Sulfation and grid corrosion are the main causes of increased internal resistance. Temperature also affects the resistance; heat lowers it and cold raises it.

Alkaline, carbon-zinc and other primary batteries have relatively high internal resistance, and this relegates their use to low-current applications such as flashlights, remote controls, portable entertainment devices and kitchen clocks. As the batteries discharge, the resistance increases further. This explains why regular alkaline cells have a relatively short runtime in digital cameras. The high internal resistance limits most primary batteries to “soft” applications, and using them to drive power tools that draw high amperage is unthinkable.

Elevated Self-discharge

All batteries are affected by self-discharge. Self-discharge is not a manufacturing defect per se, although poor manufacturing practices and improper handling can promote the problem. The amount of electrical leakage varies with chemistry, and primary cells, such as lithium and alkaline, are among the best in retaining the energy. Nickel-based rechargeable systems, in comparison, leak the most and need recharging if the battery has not been used for a few days. High-performance nickel-based batteries are subject to higher self-discharge than the standard versions with lower energy densities. Figure 6 illustrates in the form of leaking fluids the self-discharge of a battery.

Effects of high self-discharge

Figure 6: Effects of high self-discharge

Self-discharge increases with age, cycling and elevated temperature. Discard a battery if the self-discharge reaches 30 percent in 24 hours.

Courtesy of Cadex

The energy loss is asymptotical, meaning that the self-discharge is highest right after charge and then tapers off. Nickel-based batteries lose 10 to 15 percent of their capacity in the first 24 hours after charge, then 10 to 15 percent per month. Figure 7 shows the typical loss of a nickel-based battery while in storage.

Self-discharge as a function of time

 

Figure 7: Self-discharge as a function of time

The discharge is highest right after charge and tapers off. The graph shows self-discharge of a nickel-based battery. Lead- and lithium-based system have a lower self-discharge.

Courtesy of Cadex

One of the best batteries in terms of self-discharge is lead acid; it loses only five percent per month. This chemistry also has the lowest specific energy and is ill suited for portable use. Lithium-ion self-discharges about five percent in the first 24 hours and 1 to 2 percent thereafter. The need for the protection circuit increases the discharge by another three percent per month.

The self-discharge on all battery chemistries increases at higher temperatures and the rate typically doubles with every 10°C (18°F). A noticeable energy loss occurs if a battery is left in a hot vehicle. Cycling and aging also increase self-discharge. Nickel-metal-hydride is good for 300-400 cycles, whereas the standard nickel-cadmium lasts over 1,000 cycles before elevated self-discharge starts interfering with performance. The self-discharge on an older nickel-based battery can get so bad that the pack loses its energy mainly through leakage rather than normal use during the day. Discard a battery if the self-discharge reaches 30 percent in 24 hours.

The self-discharge of Li-ion is reasonably steady throughout the service life and does not increase noticeably with age, unless there is a cell anomaly caused by separator damage when microscopic metal particles group together. Improved manufacturing methods have minimized this problem on newer batteries.Table 8 reveals the self-discharge rate per month at various temperatures and state-of-charge conditions.

Charge condition

0°C (32°F)

25°C (77°F)

60°C (140°F)

Full charge

40–60% charge

6%

2%

20%

4%

35%

15%

Table 8: Self-discharge of Li-ion at various temperatures and state-of-charge
Self-discharge increases with rising temperature and higher SoC.

Once present, the high self-discharge of a flooded lead acid battery cannot be reversed. Factors leading to this failure are sludge buildup in the sediment trap on the bottom of the container. The sludge is semi-conductive, and when substance reaches to the plates a soft short occurs. On nickel-based batteries, a weakened or damaged separator is the cause of high self-discharge. Contributing factors are crystalline formation (memory), permitting the battery to “cook” in the charger or exposing it to repeated deep discharge cycles. A faulty separator also increases the self-discharge in lithium-ion batteries. In extreme cases, heat generated by the electrical leak further weakens the damaged separator. This can lead to a thermal breakdown.

Premature Voltage Cut-off

Not all stored battery energy can or should be used on discharge, and some reserve is almost always left behind when the equipment cuts off. There are several reasons for this.

Most cell phones, laptops and other portable devices turn off when the lithium-ion battery reaches 3V/cell on discharge. The manufacturers choose this relatively high voltage threshold to allow for some self-discharge while in storage, giving a grace period before the protection circuit opens at about 2.5V/cell.

A hybrid battery on a car never fully discharges and operates on a state-of-charge of 20 to 80 percent. This is the most effective working bandwidth of the battery, and staying within this range delivers the longest service life. A deep discharge with a full recharge causes undue stress to any battery, including Li-ion. Nickel-based batteries are similar, and because of reduced charge acceptance and heat buildup above the 80 percent SoC, the batteries are seldom fully charged. The emphasis on an electric powertrain is on maximizing service life rather than optimizing runtime (as is the case with consumer products).

Power tools and medical devices that draw high currents push the battery voltage to an early cut-off. This is especially true if one of the cells has a high internal resistance, or when the battery is operating at cold temperatures. These batteries may still have ample capacity left after the “cut-off” and when discharging at moderate load, a battery analyzer may read a residual capacity of 30 percent. Figure 9 illustrates the cut-off voltage graphically.

Illustration of equipment with high cut-off voltage

 

 

Figure 9: Illustration of equipment with high cut-off voltage

Portable devices do not utilize all available battery power and leave some energy behind.

Courtesy of Cadex 


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Comments

On May 31, 2011 at 11:41pm
Dave Bulman wrote:

Hi,
In the paragraph below (taken from the URL: http://batteryuniversity.com/learn/article/four_renegades_of_battery_failure) I believe there is a mistake.  Where it refers to the term “milliohms” the symbol is shown as “mW” instead of m-ohms or its equivalent greek symbol. As it reads mW is for milli-watts.

“Rising Internal Resistance

High capacity has limited use if the battery is unable to deliver the stored energy effectively. To bring the power out, the battery needs low internal resistance. Measured in milliohms (mW), resistance is the gatekeeper of the battery; the lower the value, the less restriction the pack encounters. This is especially important with heavy loads and high current pulses, as elevated resistance causes the voltage to collapse and trigger an earlyshutdown. The device turns off and valuable energy is left behind. Figure 2 illustrates batteries with low and high internal resistance as free-flowing and restricted taps.”

On June 1, 2011 at 8:20am
Cadex Electronics Inc. wrote:

Thanks Dave, we have corrected that, great catch.

Brandon

On November 21, 2011 at 9:29am
Roy fritz wrote:

A question. Can the used battery acid be used in another battery? I do not know if it breaks down or not.

On December 25, 2011 at 5:29pm
Eric Don wrote:

I have a question about storage of flashlight batteries, specifically C and D batteries. I read that when you store these types of batteries, it is important that the terminals don’t touch each other. Specifically, Why is that important?

On December 17, 2012 at 10:23am
Dave Dutton wrote:

I am trying to learn the best temperature at which to charge AND discharge my Lipos for optimal life and / or performance..

On May 2, 2014 at 7:45pm
Rene Charton wrote:

Can the used battery acid be used in another battery?
If acid from an old battery is used, is there not the problem that it might contain contamination of metal ions other than lead which might be detrimental?