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When
was the battery invented?
(BU2)
One of the most important discoveries in the last 400 years has been
electricity. You may ask, "Has electricity been around that long?"
The answer is "yes", and perhaps much longer. Surprisingly,
electricity only became useful to humanity in the late 1800s.
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Figure
1: Prehistoric batteries
Clay jar with iron rod surrounded by copper cylinder. When filled
with vinegar + an electrolytic, solution produces 1.1 volts
DC (circa. 250 BC to 640 ADO).
It is believed that the Parthians who ruled Baghdad (circa 250
BC) used batteries to electroplate silver.
The Egyptians are said to have electroplated antimony onto copper
over 4300 years ago. |
The earliest known methods of generating electricity were by creating
a static charge. Alessandro Volta (1745-1827) invented the so-called
"electric pistol" by which an electrical wire was placed
in a jar filled with methane gas. By sending an electrical spark through
the wire, the jar would explode.
Volta then thought of using this invention to provide long distance
communications, albeit only one Boolean bit. An iron wire supported
by wooden poles was to be strung from Como to Milan in Italy. At the
receiving end, the wire would terminate in a jar filled with methane
gas. On command, an electrical spark is sent by wire that would cause
a detonation to signal a coded event. This communications link was
never built.
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Figure
2: Volta and his battery.
In 1800, Alessandro Volta invented the first modern electric
battery.
Volta demonstrated that an electrical current is generated when
metals and chemicals come into contact. |
The next stage of generating electricity was through electrolysis.
Volta discovered in 1800 that a continuous flow of electrical force
was possible when using certain fluids as conductors to promote a
chemical reaction between metals. Volta discovered further that the
voltage would increase when voltaic cells were stacked. This led to
the invention of the battery.
From the availability of a battery, experiments were no longer limited
to a brief display of sparks that lasted a fraction of a second. A
seemingly endless stream of electric current was now available.
In the early 1800, France was approaching the height of scientific
advancements and new ideas were welcomed with open arms to support
the political agenda. By invitation, Volta addressed the Institute
of France in a series of lectures in which Napoleon Bonaparte was
present. Napoleon himself helped with the experiments, drawing sparks
from the battery, melting a steel wire, discharging an electric pistol
and decomposing water into its elements.
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Figure
3: Volta's experimentations at the French National Institute
in November of 1800 in which Napoleon Bonaparte was present.
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©
Cadex Electronics Inc.
In
1802, Dr. William Cruickshank designed the first electric battery capable of mass
production. Cruickshank arranged square sheets of copper soldered at their ends,
intermixed with sheets of zinc of equal size. These sheets were placed into a
long rectangular wooden box that was sealed with cement. Grooves in the box held
the metal plates in position. The box was filled with an electrolyte of brine,
or watered down acid. New discoveries were made when Sir Humphry Davy
installed the largest and most powerful electric battery in the vaults of the
Royal Institution of London. He connected the battery to charcoal electrodes and
produced the first electric light. Witnesses reported that his voltaic arc lamp
produced "the most brilliant ascending arch of light ever seen."
All batteries at this time were primary cells, meaning that they could not
be recharged. In 1859, the French physicist Gaston Planté invented the
first rechargeable battery. This secondary battery was based on lead acid, a chemistry
that is still used today.
Figure 2:
History of battery development. The battery may be much older. It is
believed that the Parthians who ruled Baghdad (ca. 250 BC) used batteries to electroplate
silver. The Egyptians are said to have electroplated antimony onto copper over
4300 years ago.
The third, and most significant, method of generating electricity was discovered
relatively late - electricity through magnetism. In 1820, André-Marie Ampère
(1775-1836) had noticed that wires carrying an electric current were at times
attracted to one another, while at other times repelled. In 1831, Michael Faraday
(1791-1867) demonstrated how a copper disc was able to provide a constant flow
of electricity when revolved in a strong magnetic field. Faraday and his research
team succeeded in generating an endless electrical force as long as the movement
between a coil and magnet continued. In 1899, Waldmar Jungner from Sweden
invented the nickel-cadmium battery. In 1947, Neumann succeeded in completely
sealing the cell. These advances led to the modern sealed nickel-cadmium battery
in use today. Research of the nickel-metal-hydride system started in
the 1970s but the metal hydride alloys were unstable in the cell environment.
New hydride alloys were developed in the 1980s that improved the stability. nickel-metal-hydride
became commercially available in the 1990s. The first primary lithium
batteries appeared in early 1970s. Attempts to develop rechargeable lithium batteries
followed in the 1980s but failed due to safety problems. Because of inherent instability
of lithium metal, especially during charging, research shifted to a non-metallic
lithium battery using lithium ions. Although lower in energy density than lithium
metal, lithium?ion is safe, provided certain precautions are met when charging
and discharging. In 1991, the Sony Corporation commercialized the first lithium-ion
battery. As
awkward and unreliable the early batteries may have been, our descendants may
one day look at today's technology in a similar way to how we view our predecessors'
clumsy experiments of 200 years ago. _________________________
Created: April 2003, Last edited: February 2007
About the
Author Isidor Buchmann is the founder and CEO of Cadex Electronics Inc.,
in Vancouver BC. Mr. Buchmann has a background in radio communications and
has studied the behavior of rechargeable batteries in practical, everyday applications
for two decades. Award winning author of many articles and books on batteries,
Mr. Buchmann has delivered technical papers around the world. Cadex Electronics
is a manufacturer of advanced battery chargers, battery analyzers and PC software.
For product information please visit www.cadex.com.
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©
Copyright 2003 - 2005 Isidor Buchmann
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