BU-806a: How Heat and Loading affect Battery Life
Learn about the temperature and how start-stop shortens the life of a starter battery
Heat is a killer of all batteries, but high temperatures cannot always be avoided. This is the case with a battery inside a laptop, a starter battery under the hood of a car and stationary batteries in a tin shelter under the hot sun. As a guideline, each 8°C (15°F) rise in temperature cuts the life of a sealed lead acid battery in half. This means that a VRLA battery for stationary applications specified to last for 10 years at 25°C (77°F) would only live 5 years if continuously exposed to 33°C (92°F) and 30 months if kept at a constant desert temperature of 41°C (106°F). Once the battery is damaged by heat, the capacity cannot be restored.
According to the 2010 BCI Failure Mode Study, starter batteries have become more heat-resistant. In the 2000 study, a rise in temperature of 7°C (12°F) affected battery life by roughly one year; in 2010 the heat tolerance has been widened to 12°C (22°F). Other statistics reveal that in 1962, a starter battery lasted 34 months; technical improvements increased the life expectancy in 2000 to 41 months. In 2010, BCI reported an average age of 55 months for starter batteries, with the cooler North attaining 59 months and the warmer South 47 months. Colloquial evidence in 2015 revealed that a battery kept in the trunk of a car lasted one year longer than if positioned in the engine compartment.
The life of a battery also depends on the activity, and the service life is shortened if the battery is stressed with frequent discharge. Cranking the engine a few times a day poses little stress on a starter battery, but this changes in the start-stop operation of a micro-hybrid. The micro-hybrid turns the internal combustion engine (ICE) off at red traffic lights and restarts it when the traffic flows again, resulting in about 2,000 micro-cycles per year. Data obtained from car manufacturers shows a capacity drop to about 60 percent after 2 years of use. To increase cycle life, automakers use specialty AGM and other systems(See BU-211: Alternate Battery Systems)
Figure 1 shows a capacity drop from 100 percent to about 50 percent after the battery had been exposed to 700 micro cycles. The simulated start-stop test was performed in the Cadex laboratories. CCA remains high and only shows a decline after about 2,000 cycles.
Figure 1: Capacity-drop of a starter battery in start-stop configuration [1]
The capacity drops to about 50 percent after 2 years of use. AGM battery is more robust.
Test method:
The battery was fully charged and then discharged to 70% to resemble SoC of a micro hybrid in real life. The battery was then discharged at 25A for 40 seconds to simulate the engine off with the headlights on. To simulate cranking and driving, the battery was briefly discharged at 400A and then recharged. CCA was taken with the Spectro CA-12.
When connected in series, the voltage of each cell must be uniform, and this is especially important in large stationary battery systems. With time, individual cells fall out of line but applying an equalizing charge every 6 months or so should bring the cells back to similar voltage levels. (See BU-404: Equalizing Charge) What makes this service so difficult is providing the right remedy to each cell. While equalizing will boost the needy cells, the healthy cell gets stressed if the equalizing charge is applied carelessly. Gel and AGM batteries have lower overcharge acceptance than the flooded version and different equalizing conditions apply.
Flooded lead acid batteries are one of the most reliable systems and are well suited for hot climates. With good maintenance these batteries last up to 20 years. The disadvantages are the need for watering and good ventilation.
When VRLA was introduced in the 1980s, manufacturers claimed similar life expectancy to the flooded systems, and the telecom industry was enticed to switch to these maintenance-free batteries. By mid-1990 it became apparent that the life of VRLA did not live up to the flooded type; the typical service life of the VRLA is 5–10 years, less than half of the flooded equivalent. It was furthermore noticed that exposing VRLA batteries to temperatures above 40°C (104°F) could cause a thermal runaway due to dry-out.
North American Automotive Battery Failures
The 2005 failure-mode study was carried out by Douglas, East Penn., Exide Technologies and Johnson Controls. The sample battery pool included 2681 batteries tested between 2003 and 2004. The highlights include:
Battery life on average was 50 months. This is an improvement from earlier years that only had 41 months (2000) and 34 months (1962). Improved materials are prolonging battery life.
Northern and southern areas in North America deliver different life spans. Batteries in warmer climates die sooner than in cooler regions. See Figure 2.
Shorted cells and grid failures are the leading causes of battery failures in this survey.
Figure 2: Failure mode as a function of region relating to temperature [2]
Batteries used in the northern area of North America last longer than those in the south.
European Automotive Battery Failure
Figure 3 summarizes the failure-mode distribution of more than 800 AGM starter batteries carried out by Johnson Controls Power Solutions EMEA. The results were presented at AABC Europe 2017 in Mainz, Germany.
Figure 3: Failure mode analysis in Europe [3]
The largest failure is mass wear-out as a function of usage reflecting in capacity fade and a rise of internal resistance.
Table 1 summarizes the cause of failure derived from the JCI study.
| Ratio | Cause | Diagnostics |
|---|---|---|
| 47.8% | Mass wear-out, normal use | Loss of capacity, rise in resistance. Capacity estimation is most predictive |
| 23% | Battery has low charge | Use voltmeter in open circuit when battery has rested |
| 14.6% | No fault found | Better test methods puts these batteries back in service |
| 12.5% | High internal resistance | Can be identified with battery testers measuring internal resistance |
| 1.6% | Container damaged | Cannot be repaired in most cases |
| 0.5% | Manufacturing defect | Manufacturers claim that most warranty causes are user induced. |
Table 1: Cause of failure by percentage of over 800 AGM batteries at end-of-life
The above JCI study identifying end of battery life provides similar results to the test performed by a German luxury car maker in ca 2007 involving 175 starter batteries. In this test, heat failed batteries (high internal resistance) were eliminated and the results were plotted in Figure 4. The horizontal axis represents capacity; internal resistance correlating to CCA is on the vertical axis. CCA was measured according to DIN and IEC standards.
The end-of-life of most batteries occurs by passing through the Capacity Line located on the left of the green field in Figure 4. Very few batteries failed by dropping through the CCA Line. Capacity fade occurs through normal use mostly due to loss of active mass. Auxiliary power, such as start-stop, heating elements and mechanical door actions accelerate capacity loss. Increased internal resistance is a side effect of the active mass loss, but capacity estimation is the more reliable predictor of end-of-life. This is highlighted with the batteries sitting gray dot. Also see: BU-806: Tracking Battery Capacity and Resistance as part of Aging
Figure 4: Capacity and CCA of 175 aging starter batteries
Most batteries pass through the Capacity Line; few fail because of low CCA. The batteries were trunk mounted and driven in a moderate climate.
Note: Test was done by a German luxury car maker. Heat damaged batteries were eliminated.
Test Method: Capacity and CCA were tested according to DIN and IEC standards.
Comments
Some makers of battery testers claim to measuring capacity when only reading the internal resistance. Advertising features that lay outside of the equipment’s capabilities confuses the industry into believing that complex tests can be done with basic methods. Resistance-based instruments can identify a dying or dead battery, but so does the user by poor cranking performance. See also BU-905: Testing Lead Acid Batteries
References
[1] Courtesy of Cadex, 2010
[2] Source: Survey carried out by Douglas, East Penn., Exide Technologies, and Johnson Controls
[3] Source: Johnson Controls Power Solutions EMEA at AABC Europe 2017 in Mainz, Germany
Last Updated: 2-Nov-2021
Batteries In A Portable World
The material on Battery University is based on the indispensable new 4th edition of "Batteries in a Portable World - A Handbook on Rechargeable Batteries for Non-Engineers" which is available for order through Amazon.com.
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Table of Contents
-
Introduction 4>
- BU-001: Sharing Battery Knowledge
- BU-002: Introduction
- BU-003: Dedication
-
Crash Course on Batteries 4>
- BU-101: When Was the Battery Invented?
- BU-102: Early Innovators
- BU-103: Global Battery Markets
- BU-103a: Battery Breakthroughs: Myth or Fact?
- BU-104: Getting to Know the Battery
- BU-104a: Comparing the Battery with Other Power Sources
- BU-104b: Battery Building Blocks
- BU-104c: The Octagon Battery – What makes a Battery a Battery
- BU-105: Battery Definitions and what they mean
- BU-106: Advantages of Primary Batteries
- BU-106a: Choices of Primary Batteries
- BU-107: Comparison Table of Secondary Batteries
-
Battery Types 4>
- BU-201: How does the Lead Acid Battery Work?
- BU-201a: Absorbent Glass Mat (AGM)
- BU-201b: Gel Lead Acid Battery
- BU-202: New Lead Acid Systems
- BU-203: Nickel-based Batteries
- BU-204: How do Lithium Batteries Work?
- BU-205: Types of Lithium-ion
- BU-206: Lithium-polymer: Substance or Hype?
- BU-208: Cycling Performance
- BU-209: How does a Supercapacitor Work?
- BU-210: How does the Fuel Cell Work?
- BU-210a: Why does Sodium-sulfur need to be heated
- BU-210b: How does the Flow Battery Work?
- BU-211: Alternate Battery Systems
- BU-212: Future Batteries
- BU-214: Summary Table of Lead-based Batteries
- BU-215: Summary Table of Nickel-based Batteries
- BU-216: Summary Table of Lithium-based Batteries
- BU-217: Summary Table of Alternate Batteries
- BU-218: Summary Table of Future Batteries
-
Packaging and Safety 4>
- BU-301: A look at Old and New Battery Packaging
- BU-301a: Types of Battery Cells
- BU-302: Series and Parallel Battery Configurations
- BU-303: Confusion with Voltages
- BU-304: Why are Protection Circuits Needed?
- BU-304a: Safety Concerns with Li-ion
- BU-304b: Making Lithium-ion Safe
- BU-304c: Battery Safety in Public
- BU-305: Building a Lithium-ion Pack
- BU-306: What is the Function of the Separator?
- BU-307: How does Electrolyte Work?
- BU-308: Availability of Lithium
- BU-309: How does Graphite Work in Li-ion?
- BU-310: How does Cobalt Work in Li-ion?
- BU-311: Battery Raw Materials
-
Charge Methods 4>
- BU-401: How do Battery Chargers Work?
- BU-401a: Fast and Ultra-fast Chargers
- BU-402: What Is C-rate?
- BU-403: Charging Lead Acid
- BU-404: What is Equalizing Charge?
- BU-405: Charging with a Power Supply
- BU-406: Battery as a Buffer
- BU-407: Charging Nickel-cadmium
- BU-408: Charging Nickel-metal-hydride
- BU-409: Charging Lithium-ion
- BU-409a: Why do Old Li-ion Batteries Take Long to Charge?
- BU-409b: Charging Lithium Iron Phosphate
- BU-410: Charging at High and Low Temperatures
- BU-411: Charging from a USB Port
- BU-412: Charging without Wires
- BU-413: Charging with Solar, Turbine
- BU-413a: How to Store Renewable Energy in a Battery
- BU-414: How do Charger Chips Work?
- BU-415: How to Charge and When to Charge?
-
Discharge Methods 4>
- BU-501: Basics about Discharging
- BU-501a: Discharge Characteristics of Li-ion
- BU-502: Discharging at High and Low Temperatures
- BU-503: Determining Power Deliver by the Ragone Plot
- BU-504: How to Verify Sufficient Battery Capacity
-
"Smart" Battery 4>
- BU-601: How does a Smart Battery Work?
- BU-602: How does a Battery Fuel Gauge Work?
- BU-603: How to Calibrate a “Smart” Battery
- BU-603a: Calibrating SMBus Batteries with Impedance Tracking
- BU-604: How to Process Data from a “Smart” Battery
- Testing and Calibrating Smart Batteries
-
From Birth to Retirement 4>
- BU-701: How to Prime Batteries
- BU-702: How to Store Batteries
- BU-703: Health Concerns with Batteries
- BU-704: How to Transport Batteries
- BU-704a: Shipping Lithium-based Batteries by Air
- BU-704b: CAUTION & Overpack Labels
- BU-704c: Class 9 Label
- BU-704d: NFPA 704 Rating
- BU-704e: Battery for Personal and Fleet Use
- BU-705: How to Recycle Batteries
- BU-705a: Battery Recycling as a Business
- BU-706: Summary of Do's and Don'ts
-
How To Prolong Battery Life 4>
-
General 4>
- BU-801: Setting Battery Performance Standards
- BU-801a: How to Rate Battery Runtime
- BU-801b: How to Define Battery Life
- BU-802: What Causes Capacity Loss?
- BU-802a: How does Rising Internal Resistance affect Performance?
- BU-802b: What does Elevated Self-discharge Do?
- BU-802c: How Low can a Battery be Discharged?
- BU-803: Can Batteries Be Restored?
- BU-803a: Cell Matching and Balancing
- BU-803b: What causes Cells to Short?
- BU-803c: Loss of Electrolyte
-
Lead Acid 4>
- BU-804: How to Prolong Lead-acid Batteries
- BU-804a: Corrosion, Shedding and Internal Short
- BU-804b: Sulfation and How to Prevent it
- BU-804c: Acid Stratification and Surface Charge
- BU-805: Additives to Boost Flooded Lead Acid
- BU-806: Tracking Battery Capacity and Resistance as part of Aging
- BU-806a: How Heat and Loading affect Battery Life
-
Nickel-based 4>
- BU-807: How to Restore Nickel-based Batteries
- BU-807a: Effect of Zapping
-
Lithium-ion 4>
- BU-808: How to Prolong Lithium-based Batteries
- BU-808a: How to Awaken a Sleeping Li-ion
- BU-808b: What Causes Li-ion to Die?
- BU-808c: Coulombic and Energy Efficiency with the Battery
- BU-809: How to Maximize Runtime
- BU-810: What Everyone Should Know About Aftermarket Batteries
- BU-811: Assuring Minimum Operational Reserve Energy (MORE)
-
Battery Testing and Monitoring 4>
- BU-901: Fundamentals in Battery Testing
- BU-901b: How to Measure the Remaining Useful Life of a Battery
- BU-902: How to Measure Internal Resistance
- BU-902a: How to Measure CCA
- BU-903: How to Measure State-of-charge
- BU-904: How to Measure Capacity
- BU-905: Testing Lead Acid Batteries
- BU-905a: Testing Starter Batteries in Vehicles
- BU-905b: Knowing when to Replace a Starter Battery
- BU-906: Testing Nickel-based Batteries
- BU-907: Testing Lithium-based Batteries
- BU-907a: Battery Rapid-test Methods
- BU-907b: Advancements in Battery Testing
- BU-907c: Cloud Analytics in Batteries
- BU-908: Battery Management System (BMS)
- BU-909: Battery Test Equipment
- BU-910: How to Repair a Battery Pack
- BU-911: How to Repair a Laptop Battery
- BU-915: Testing Battery with EIS
- BU-916: Deep Battery Diagnostics
- BU-917: In Search for Performance Transparency with Batteries
- BU-918: Battery Endurance Plan
- BU-919: Building a Matrix to test Batteries
- BU-920: Matrix Library
- BU-921: Testing Batteries by Multi-Model EIS
-
Amazing Value of a Battery 4>
- BU-1001: Batteries in Industries
- BU-1002: Electric Powertrain, then and now
- BU-1002a: Hybrid Electric Vehicles and the Battery
- BU-1002b: Environmental Benefit of the Electric Powertrain
- BU-1003: Electric Vehicle (EV)
- BU-1003a: Battery Aging in an Electric Vehicle (EV)
- BU-1004: Charging an Electric Vehicle
- BU-1005: Does the Fuel Cell-powered Vehicle have a Future?
- BU-1006: Cost of Mobile and Renewable Power
- BU-1007: Net Calorific Value
- BU-1008: Working towards Sustainability
- BU-1009: Battery Paradox - Afterword
-
Information 4>
- BU-1101: Glossary
- BU-1102: Abbreviations
- BU-1103: Bibliography
- BU-1104: About the Author
- BU-1105: About Cadex (Sponsor)
- BU-1106: Author's Creed
- BU-1107: Disclaimer
- BU-1108: Copyright
-
Learning Tools 4>
- BU-1501 Battery History
- BU-1502 Basics about Batteries
- BU-1503 How to Maintain Batteries
- BU-1504 Battery Test & Analyzing Devices
- BU-1505 Short History of Cadex
-
Battery Articles 4>
- Perception of a Battery Tester
- Green Deal
- Risk Management in Batteries
- Predictive Test Methods for Starter Batteries
- Why Mobile Phone Batteries do not last as long as an EV Battery
- Battery Rapid-test Methods
- How to Charge Li-ion with a Parasitic Load
- Ultra-fast Charging
- Assuring Safety of Lithium-ion in the Workforce
- Diagnostic Battery Management
- Tweaking the Mobile Phone Battery
- Battery Test Methods
- Battery Testing and Safety
- How to Make Battery Performance Transparent
- Battery Diagnostics On-the-fly
- Making Battery State-of-health Transparent
- Batteries will eventually die, but when and how?
- Why does Pokémon Go rob so much Battery Power?
- How to Care for the Battery
- Tesla’s iPhone Moment — How the Powerwall will Change Global Energy Use
- Painting the Battery Green by giving it a Second Life
- Charging without Wires — A Solution or Laziness
- What everyone should know about Battery Chargers
- A Look at Cell Formats and how to Build a good Battery
- Battery Breakthroughs — Myth or Fact?
- Rapid-test Methods that No Longer Work
- Shipping Lithium-based Batteries by Air
- How to make Batteries more Reliable and Longer Lasting
- What causes Lithium-ion to die?
- Safety of Lithium-ion Batteries
- Recognizing Battery Capacity as the Missing Link
- Managing Batteries for Warehouse Logistics
- Caring for your Starter Battery
- Giving Batteries a Second Life
- How to Make Batteries in Medical Devices More Reliable
- Possible Solutions for the Battery Problem on the Boeing 787
- Impedance Spectroscopy Checks Battery Capacity in 15 Seconds
- How to Improve the Battery Fuel Gauge
- Examining Loading Characteristics on Primary and Secondary Batteries
-
Language Pool 4>
- BU-001: Compartir conocimiento sobre baterías
- BU-002: Introducción
- BU-003: Dedicatoria
- BU-104: Conociendo la Batería
- BU-302: Configuraciones de Baterías en Serie y Paralelo
-
Batteries in a Portable World book 4>
- Change-log of “Batteries in a Portable World,” 4th edition: Chapters 1 - 3
- Change-log of “Batteries in a Portable World,” 4th edition: Chapters 4 - 10