BU-309: How does Graphite Work in Li-ion?

Understanding the key raw materials of Li-ion

In 2015, the media predicted heavy demand for graphite to satisfy the growth of Li-ion batteries used in electric vehicles. Speculation arose that graphite could be in short supply because a large EV battery requires about 25kg (55 lb) of graphite for the Li-ion anode. Although price and consumption has been lackluster, there are indications that the demand is tightening.

Producing anode-grade graphite with 99.99 percent purity is expensive and the process creates waste. The end-cost is not so much the material but the purification process. Recycling old Li-ion to retrieve graphite will not solve this because of the tedious purification process.

Carbon and graphite are related substances. Graphite is an allotrope of carbon, a structural modification that occurs by bonding the elements together in a different manner. Graphite is the most stable form of carbon. The diamond, a metastable allotrope of carbon known for its excellent physical qualities, is less stable than graphite; yet graphite is soft and malleable.

Graphite comes from the Greek word “graphein.” It is heat-resistant, electrically and thermally conductive, chemically passive (corrosion-resistant) and lighter than aluminum. Beside Li-ion anodes, high-grade graphite is also used in fuel cells, solar cells, semiconductors, LEDs, and nuclear reactors.

A carbon fiber is a long, thin strand of about 5–10µm in diameter, one-tenth the thickness of a human hair. The carbon atoms are bonded together in microscopic crystals and are extremely strong. They are woven in a textile fashion and mixed with a polymer matrix, which is a hardened form of carbon fiber that is as strong as steel but lighter. These materials are used in golf clubs and bicycle frames, as well as body parts for cars and airplanes to replace aluminum. The Boeing 787 and Airbus 350X make extensive use of carbon fiber. Graphite for batteries currently accounts to only 5 percent of the global demand.

Graphite comes in two forms: natural graphite from mines and synthetic graphite from petroleum coke. Both types are used for Li-ion anode material with 55 percent gravitating towards synthetic and the balance to natural graphite.

Manufacturers preferred synthetic graphite because of its superior consistency and purity to natural graphite. This is changing and with modern chemical purification processes and thermal treatment, natural graphite achieves a purity of 99.9 percent compared to 99.0 percent for the synthetic equivalent.

Purified natural flake graphite has a higher crystalline structure and offers better electrical and thermal conductivity than synthetic material. Switching to natural graphite will lower production cost with same or better Li-ion performance. Synthetic graphite for Li-ion sells for around US $10,000 per ton whereas spherical graphite made from natural flake sells for US $7,000 (2015 prices).

Unprocessed natural graphite is much cheaper, and besides cost, natural graphite is more environmentally friendly than synthetic graphite; it also forms the base for graphene, a scientist’s dream. At the end of 2016, natural graphite accounts for 60-65% of the market share; synthetic is around 30% and alternatives such as lithium titanate, silicon and tin is around 5%.


Graphene

Graphene is an allotrope of carbon in the form of a two-dimensional hexagonal lattice. Presented in a sheet of pure carbon, graphene is only one atom thick. It is flexible, transparent, impermeable to moisture, stronger than diamonds and more conductive than gold. Experts hint to graphene as a miracle material that will improve many products, including the battery.

Graphene anodes are said to hold energy better than graphite anodes and promise a charge time that is ten times faster than what is currently possible with Li-ion. Load capabilities should also improve; better longevity is another item on the wish-list that needs to be proven.

With traditional graphite anodes, lithium ions accumulate around the outer surface of the anode. Graphene has a more elegant solution by enabling lithium ions to pass through the tiny holes of the graphene sheets measuring 10–20nm. This promises optimal storage area and easy extraction. Once available, such a battery is estimated to store ten times more energy than Li-ion featuring regular graphite anodes.

Further improvements with graphene are achieved by adding vanadium oxide to the cathode. Experimental batteries with such an enhancement are said to recharge in 20 seconds and retain 90 percent capacity after 1,000 cycles. Graphene is also being tested in supercapacitors to improve the specific energy density, as well as in solar cells. Figure 1 illustrates the unique lattice of graphene made visible with scanning probe microscopy (SPM).
 

Graphene
Figure 1: Scanning probe microscopy (SPM) shows an image of graphene.
Graphene is a sheet of pure carbon that is one atom thick. It is flexible, transparent, impermeable to moisture, stronger than diamonds and more conductive than gold. Each carbon atom possesses three electrons that bind with the nearest neighbor atom electron, creating a chemical bond.

Source: U.S. Army Materiel Command

Scientists have theorized about the wonders of graphene for decades, but no commercial products exist that makes exclusive use of this apparent miracle material. It is likely that the marvel of graphene has been utilized unknowingly for centuries in pencils and other products. A better understanding of its mechanism will eventually lead to improved products.

Meanwhile we take the many wonderful breakthroughs published by academia and stock promoters with a grain of salt. We will embrace the super battery when it arrives but pledge to honor what we currently have by taking better care of it in the workforce. (See BU-104c: The Octagon Battery.)

Last updated 2017-05-02

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Comments

On July 3, 2015 at 6:30am
Jon wrote:

Would it not be possible to refine synthetic graphene much the same way that the natural form is? I only ask because removing “pet coke” from the environment seems healthier and more environmentally friendly.  Couple that with the concept that a higher initial purity should mean less refinement is required should also mean a more environmentally friendly solution that is also less expensive.

On January 14, 2016 at 5:11am
lal bahadur singh wrote:

CAN YOU PLESE ADVISE THE PROCESSING OF SYNTHETIC GRAPHITE FROM COAL TAR PITCH TO GRAPHITE POWDER TO BE USED IN ELECTRODE! CAN YOU ADVISE THE TRICKS OF MANUFACTURE OF SYNTHETIC GRAPHITE WHICH ATTAINS A ANODE CAPACITY OY 372 mAh/gm! plese enlighten us on this matter!

On January 19, 2016 at 11:29am
robert fennell wrote:

please send info on subject coal tar to graphite power

thank youbeing

On February 21, 2016 at 7:42am
Ajay Goyal wrote:

Amazing….. coal fired power plants are polluting the world with CO2 and other noxious emissions….. and who knows one day could be used as “Graphene”.... would help in storing energy in EV’s….. what goes round….. comes around… don’t get rid of your invetments in coal mines… who knows….!!!

On April 15, 2016 at 1:46pm
Steve Parkinson wrote:

A friend of mine has just informed me that he has a Graphite mine with 17,000,000 tonnes of surface mineral and he is looking for a buyer. The current asking price is $60 million with a $2 million commission for anyone that puts us in contact with a buyer. You can contact me at steve@spmarketing.info I will have a presentation package by the end of April 2016 if anyone is interested. Thanks.

On April 15, 2016 at 1:51pm
Steve Parkinson wrote:

I forgot to mention the mine is in Brazil near Natal.

On May 2, 2016 at 10:43am
Brenden ritter wrote:

This tech sounds like it will change th world when it becomes practical. Can anyone tell me what else needs to be solved as far as mass production goes?

On August 25, 2016 at 1:44am
William Davison wrote:

Can you comment on Grabat http://grabat.es/en/node/35.  Its in Spanish but when I used Google Translate it made some amazing claims.

” polymer made from graphene that, in the case of use in electric vehicles, would allow a range of 800 kilometers batteries. ” 

“, it has a density of 1,000 Wh / kg, a voltage of 2,3V and when it has been analyzed by independent agencies TÜV”

“According to the president, he has “enormous potential, since the speed of loading and unloading is 100 C, while a battery is 3C, and no memory effect.”

On October 31, 2016 at 12:05am
Diwakar Karuppiah wrote:

synthetic graphene has more expensive than natural one. But natural graphene is also purified by some process, is n’t it ? hence it also takes some cost. Then how the cost of synthetic is higher?

On November 10, 2016 at 6:34am
Haim Dror wrote:

What is the most high dense battery technology?

On December 1, 2016 at 3:31am
Raafat wrote:

same comment of Diwakar Karuppiah,

synthetic graphene has more expensive than natural one. But natural graphene is also purified by some process, is n’t it ? hence it also takes some cost. Then how the cost of synthetic is higher?

On June 29, 2017 at 12:42am
D.M.S Dissanayake wrote:

have you tested for graphene oxide using natural crystalline vein graphite?