Understanding the importance of low conductivity
Capacity alone is of limited use if the pack cannot deliver the stored energy effectively; a battery also needs low internal resistance. Measured in milliohms (mΩ), resistance is the gatekeeper of the battery; the lower the resistance, the less restriction the pack encounters. This is especially important on heavy loads such as power tools and electric powertrains. High resistance causes the battery to heat up and the voltage to drop under load, triggering an early shutdown. Figure 1 illustrates a battery with low internal resistance in the form of a free-flowing tap against a battery with elevated resistance in which the tap is restricted.
Figure 1: Effects of internal battery resistance
A battery with low internal resistance delivers high current on demand. High resistance causes the battery to heat up and the voltage to drop. The equipment cuts off, leaving energy behind
Courtesy of Cadex
Lead acid has a very low internal resistance and the battery responds well to high current bursts that last for a few seconds. Due to inherent sluggishness, however, lead acid does not perform well on a sustained high current discharge; the battery soon gets tired and needs a rest to recover. Some sluggishness is apparent on all batteries at different degrees but it is especially pronounced with lead acid. This hints that power delivery is not based in internal resistance alone but also on the responsiveness of the chemistry and temperature also plays a role. In this respect, nickel- and lithium-based technologies are more responsive than lead acid.
Sulfation and grid corrosion are the main contributors to the rise of the internal resistance with lead acid. Temperature also affects the resistance; heat lowers it and cold raises it. Heating the battery will momentarily lower the internal resistance to provide extra run time. This, however, does not restore the battery and will add momentary stress.
“Crystalline formation, also known as “memory,” contributes to the internal resistance on nickel-based batteries. This can often be reversed with deep-cycling. The internal resistance of Li-ion also increases with use and aging but improvements have been made with electrolyte additives to keep the buildup of films on the electrodes under control. [ See BU-808b: What causes Li-ion to Die? ]
Two methods are used to read the internal resistance of a battery: Direct current (DC) by measuring the voltage drop at a given current, and alternating current (AC) that takes reactance into account. When measuring a reactive device such as a battery, the resistance values vary greatly between the DC and AC test methods and neither reading is right or wrong. The DC reading looks at pure resistance (R) and provides true results for a DC load such as a heating element, while the AC reading includes reactive components and provides impedance (Z). Impedance provides realistic results on a digital load such as a mobile phone or an inductive motor. [ See BU-902: How to Measure Internal Resistance ]
The internal resistance of a battery does not consist of the cells alone but also includes the interconnection, fuses, protection circuits and wiring. In most cases these peripherals more than double the internals resistance and can falsify rapid-test methods. Typical readings of a single cell pack for a mobile phone and a multi-cell battery for a power tool are shown below.
Internal Resistance of a Mobile Phone Battery
|Cell, single, high capacity prismatic||50mΩ||subject to increase with age|
|PTC, welded to cable, cell||25mΩ||18–30 mΩ according to spec|
|Protection circuit, PCB||50mΩ|
|Total internal resistance||ca. 130mΩ|
Internal Resistance of a Power Pack for Power Tools
|Cells 2P4S at 2Ah/cell,||18mΩ||subject to increase with age|
|Connection, welded, each||0.1mΩ|
|Protection circuit, PCB||10mΩ|
|Total internal resistance||ca. 80mΩ|
Source: Siemens AG (2015, München)
Figures 2, 3 and 4 reflect the runtime of three batteries with similar Ah and capacities but different internal resistance when discharged at 1C, 2C and 3C. The graphs demonstrate the importance of maintaining low internal resistance, especially at higher discharge currents. The NiCd test battery comes in at 155mΩ, NiMH has 778mΩ and Li-ion has 320mΩ. These are typical resistive readings on aged but still functional batteries. See [ BU-208: Cycling Performance ] that demonstrates the relationship of capacity, internal resistance and self-discharge.
Figure 2: GSM discharge pulses at 1, 2, and 3C with resulting talk-time
The capacity of the NiCd battery is 113%; the internal resistance is 155mΩ.
Figure 3: GSM discharge pulses at 1, 2, and 3C with resulting talk-time
The capacity of the NiMH battery is 94%, the internal resistance is 320mΩ.
Figure 4: GSM discharge pulses at 1, 2, and 3C with resulting talk-time
The capacity of the Li-ion battery is 107%; the internal resistance is 778mΩ.
All three figures courtesy of Cadex
Notes: The tests were done when early mobile phones were powered by NiCd, NiMH and Li-ion. Li-ion and NiMH have since improved. The maximum GSM draw is 2.5A, representing 3C from an 800mAh pack, or three times the rated current.
Last updated 2016-01-12
Comments are intended for "commenting," an open discussion amongst site visitors. Battery University monitors the comments and understands the importance of expressing perspectives and opinions in a shared forum. However, all communication must be done with the use of appropriate language and the avoidance of spam and discrimination.
If you have a question, require further information, have a suggestion or would like to report an error, use the "contact us" form or email us at: BatteryU@cadex.com. While we make all efforts to answer your questions accurately, we cannot guarantee results. Neither can we take responsibility for any damages or injuries that may result as a consequence of the information provided. Please accept our advice as a free public support rather than an engineering or professional service.